Fungal Sterols Explained

Sterols are a small but characteristic part of mushroom chemistry. This article explains ergosterol, its link to vitamin D2 and how sterols behave in extraction.

Fungal Sterols Explained

Key takeaways

  • Sterols stabilise cell membranes; fungi use mainly ergosterol.
  • Ergosterol converts to vitamin D2 under UV light.
  • Sterols are related to triterpenes.
  • They dissolve in alcohol, not water.

Sterols are a small but characteristic part of mushroom chemistry. This article explains fungal sterols, especially ergosterol.

What are sterols?

Sterols are a group of molecules built on a four-ring structure. They help keep cell membranes stable. Animals use cholesterol; plants use phytosterols; fungi use mainly ergosterol.

Ergosterol

Ergosterol is the main sterol in most fungi, including functional mushrooms. It is so characteristic of fungi that it is used in research as a marker of fungal presence.

Ergosterol and vitamin D

When exposed to ultraviolet light, ergosterol converts to vitamin D2. This is why some mushrooms are deliberately exposed to UV light to increase their vitamin D content.

Sterols are chemically related to triterpenes, which share a similar origin. Mushrooms such as Reishi and chaga contain both.

Extraction

Sterols are not water-soluble. They dissolve in alcohol and fats, so they are captured by the alcohol stage of a dual extract.

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